Carbazole-based organogel as a scaffold to construct energy transfer arrays with controllable fluorescence emission

A diaryldiketopyrrolopyrrole derivative functionalized with phenothiazine moieties (DPPP) was synthesized and introduced into the ordered 4-(3,6-di-tert-butyl-9H-carbazol-9-yl)benzamide (TBCB) organogel system. It was found that TBCB-based gel became a scaffold to make DPPP molecules line up along t...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1991. - 24(2008), 23 vom: 02. Dez., Seite 13730-5
1. Verfasser: Yang, Xinchun (VerfasserIn)
Weitere Verfasser: Lu, Ran, Xue, Pengchong, Li, Bin, Xu, Defang, Xu, Tinghua, Zhao, Yingying
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2008
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't 4-(3,6-di-tert-butyl-9H-carbazol-9-yl)benzamide Benzamides Carbazoles Gels Pyrroles carbazole 0P2197HHHN
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520 |a A diaryldiketopyrrolopyrrole derivative functionalized with phenothiazine moieties (DPPP) was synthesized and introduced into the ordered 4-(3,6-di-tert-butyl-9H-carbazol-9-yl)benzamide (TBCB) organogel system. It was found that TBCB-based gel became a scaffold to make DPPP molecules line up along the gel fibers, resulting in new self-assembled arrays, whose XRD patterns were quite different from those of the neat TBCB gel and DPPP crystal. In the composite gel, the occurrence of a partial energy transfer from the excited light-harvesting antenna of TBCB to the DPPP acceptor was confirmed on the basis of time-dependent and time-resolved fluorescence investigations. Remarkably, the composite gel could emit intense red light or purplish white light by tuning the excitation wavelength. Such ordered soft materials with color-tunable emission may possess potential applications in sensor and photonic devices 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 7 |a 4-(3,6-di-tert-butyl-9H-carbazol-9-yl)benzamide  |2 NLM 
650 7 |a Benzamides  |2 NLM 
650 7 |a Carbazoles  |2 NLM 
650 7 |a Gels  |2 NLM 
650 7 |a Pyrroles  |2 NLM 
650 7 |a carbazole  |2 NLM 
650 7 |a 0P2197HHHN  |2 NLM 
700 1 |a Lu, Ran  |e verfasserin  |4 aut 
700 1 |a Xue, Pengchong  |e verfasserin  |4 aut 
700 1 |a Li, Bin  |e verfasserin  |4 aut 
700 1 |a Xu, Defang  |e verfasserin  |4 aut 
700 1 |a Xu, Tinghua  |e verfasserin  |4 aut 
700 1 |a Zhao, Yingying  |e verfasserin  |4 aut 
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