Electrospinning of polyvinylidene difluoride with carbon nanotubes : synergistic effects of extensional force and interfacial interaction on crystalline structures

Polyvinylidene difluoride (PVDF) solutions containing a very low concentration of single-walled carbon nanotubes (SWCNTs) and multiwalled carbon nanotubes (MWCNTs) of similar surface chemistry, respectively, were electrospun, and the nanofibers formed were collected using a modified rotating disk co...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 24(2008), 23 vom: 02. Dez., Seite 13621-6
1. Verfasser: Huang, Shu (VerfasserIn)
Weitere Verfasser: Yee, Wu Aik, Tjiu, Wuiwui Chauhari, Liu, Ye, Kotaki, Masaya, Boey, Yin Chiang Freddy, Ma, Jan, Liu, Tianxi, Lu, Xuehong
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2008
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Nanotubes, Carbon Polyvinyls polyvinylidene fluoride 24937-79-9
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520 |a Polyvinylidene difluoride (PVDF) solutions containing a very low concentration of single-walled carbon nanotubes (SWCNTs) and multiwalled carbon nanotubes (MWCNTs) of similar surface chemistry, respectively, were electrospun, and the nanofibers formed were collected using a modified rotating disk collector. The polymorphic behavior and crystal orientation of the nanofibers were studied using wide-angle X-ray diffraction and infrared spectroscopy, while the nanotube alignment and interfacial interactions in the nanofibers were probed by transmission electron microscopy and Raman spectroscopy. It is shown that the interfacial interaction between the SWCNTs and PVDF and the extensional force experienced by the nanofibers in the electrospinning and collection processes can work synergistically to induce highly oriented beta-form crystallites extensively. In contrast, the MWCNTs could not be well aligned along the nanofiber axis, which leads to a lower degree of crystal orientation 
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700 1 |a Yee, Wu Aik  |e verfasserin  |4 aut 
700 1 |a Tjiu, Wuiwui Chauhari  |e verfasserin  |4 aut 
700 1 |a Liu, Ye  |e verfasserin  |4 aut 
700 1 |a Kotaki, Masaya  |e verfasserin  |4 aut 
700 1 |a Boey, Yin Chiang Freddy  |e verfasserin  |4 aut 
700 1 |a Ma, Jan  |e verfasserin  |4 aut 
700 1 |a Liu, Tianxi  |e verfasserin  |4 aut 
700 1 |a Lu, Xuehong  |e verfasserin  |4 aut 
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