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231223s2008 xx |||||o 00| ||eng c |
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|a 10.1021/la801293e
|2 doi
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|a pubmed24n0613.xml
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|a (DE-627)NLM183856759
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|a (NLM)18939806
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Kobayashi, Katsuaki
|e verfasserin
|4 aut
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|a Fabrication of DNA nanowires by orthogonal self-assembly and DNA intercalation on a Au patterned Si/SiO2 surface
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|c 2008
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 09.01.2009
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|a Date Revised 21.11.2013
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a A novel Ru complex bearing both an acridine group and anchoring phosphonate groups was immobilized on a surface in order to capture double-stranded DNAs (dsDNAs) from solution. At low surface coverage, the atomic force microscopy (AFM) image revealed the "molecular dot" morphology with the height of the Ru complex ( approximately 2.5 nm) on a mica surface, indicating that four phosphonate anchor groups keep the Ru complex in an upright orientation on the surface. Using a dynamic molecular combing method, the DNA capture efficiency of the Ru complex on a mica surface was examined in terms of the effects of the number of molecular dots and surface hydrophobicity. The immobilized surface could capture DNAs; however, the optimal number of molecular dots on the surface as well as the optimal pull-up speed exist to obtain the extended dsDNAs on the surface. Applying this optimal condition to a Au-patterned Si/SiO 2 (Au/SiO 2) surface, the Au electrode was selectively covered with the Ru complex by orthogonal self-assembly of 4-mercaptbutylphosphonic acid (MBPA), followed by the formation of a Zr (4+)-phosphonate layer and the Ru complex. At the same time, the remaining SiO 2 surface was covered with octylphosphonic acid (OPA) by self-assembly. The selective immobilization of the Ru complex only on the Au electrode was identified by time-of-flight secondary-ion mass spectrometry (TOF-SIMS) imaging on the chemically modified Au/SiO 2 surface. The construction of DNA nanowires on the Au/SiO 2 patterned surface was accomplished by the molecular combing method of the selective immobilized Ru complex on Au electrodes. These interconnected nanowires between Au electrodes were used as a scaffold for the modification of Pd nanoparticles on the DNA. Furthermore, Cu metallization was achieved by electroless plating of Cu metal on a priming of Pd nanoparticles on the Pd-covered DNA nanowires. The resulting Cu nanowires showed a metallic behavior with relatively high resistance
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a 3-(4-methoxybenzoyl)propionic acid
|2 NLM
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|a Intercalating Agents
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|a Metals
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|a Organophosphonates
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|a Phenyl Ethers
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|a Propionates
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|a Palladium
|2 NLM
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|a 5TWQ1V240M
|2 NLM
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|a Gold
|2 NLM
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|a 7440-57-5
|2 NLM
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|a Silicon Dioxide
|2 NLM
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|a 7631-86-9
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|a DNA
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|a 9007-49-2
|2 NLM
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|a Zirconium
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|a C6V6S92N3C
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|a Silicon
|2 NLM
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|a Z4152N8IUI
|2 NLM
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|a Tonegawa, Naoya
|e verfasserin
|4 aut
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|a Fujii, Sho
|e verfasserin
|4 aut
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|a Hikida, Jiro
|e verfasserin
|4 aut
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|a Nozoye, Hisakazu
|e verfasserin
|4 aut
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|a Tsutsui, Ken
|e verfasserin
|4 aut
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|a Wada, Yasuo
|e verfasserin
|4 aut
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|a Chikira, Makoto
|e verfasserin
|4 aut
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|a Haga, Masa-Aki
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 24(2008), 22 vom: 18. Nov., Seite 13203-11
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:24
|g year:2008
|g number:22
|g day:18
|g month:11
|g pages:13203-11
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|u http://dx.doi.org/10.1021/la801293e
|3 Volltext
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|d 24
|j 2008
|e 22
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|h 13203-11
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