Layer-by-layer-assembled multilayer films of polyelectrolyte-stabilized surfactant micelles for the incorporation of noncharged organic dyes

Noncharged pyrene molecules were incorporated into multilayer films by first loading pyrene into poly(acrylic acid) (PAA)-stabilized cetyltrimethylammonium bromide (CTAB) micelles (noted as PAA&(PyCTAB)) and then layer-by-layer (LbL) assembled with poly(diallyldimethylammonium chloride) (PDDA)....

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Détails bibliographiques
Publié dans:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 24(2008), 22 vom: 18. Nov., Seite 12986-9
Auteur principal: Liu, Xiaokong (Auteur)
Autres auteurs: Zhou, Lu, Geng, Wei, Sun, Junqi
Format: Article en ligne
Langue:English
Publié: 2008
Accès à la collection:Langmuir : the ACS journal of surfaces and colloids
Sujets:Journal Article
Description
Résumé:Noncharged pyrene molecules were incorporated into multilayer films by first loading pyrene into poly(acrylic acid) (PAA)-stabilized cetyltrimethylammonium bromide (CTAB) micelles (noted as PAA&(PyCTAB)) and then layer-by-layer (LbL) assembled with poly(diallyldimethylammonium chloride) (PDDA). The stable incorporation of pyrene into multilayer films was confirmed by quartz crystal microbalance (QCM) measurements and UV-vis absorption spectroscopy. The resultant PAA&(Py@CTAB)/PDDA multilayer films show an exponential growth behavior because of the increased surface roughness with increasing number of film deposition cycles. The present study will open a general and cost-effective avenue for the incorporation of noncharged species, such as organic molecules, nanoparticles, and so forth, into LbL-assembled multilayer films by using polyelectrolyte-stabilized surfactant micelles as carriers
Description:Date Completed 09.01.2009
Date Revised 12.11.2008
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1520-5827
DOI:10.1021/la802674h