Three-dimensional molecular packing of thin organic films of PTCDI-C8 determined by surface X-ray diffraction

We have determined the full molecular 3D packing of thin organic films of the archetypical organic n-type semiconductor N, N'-dioctyl-3,4:9,10-perylene tetracarboxylic diimide (PTCDI-C 8) by surface X-ray crystallography. We show that PTCDI-C 8 forms smooth layered films on Al 2O 3 (11-20) with...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 24(2008), 22 vom: 18. Nov., Seite 12742-4
1. Verfasser: Krauss, Tobias N (VerfasserIn)
Weitere Verfasser: Barrena, Esther, Zhang, Xue N, de Oteyza, Dimas G, Major, János, Dehm, Volker, Würthner, Frank, Cavalcanti, Leide P, Dosch, Helmut
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2008
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a We have determined the full molecular 3D packing of thin organic films of the archetypical organic n-type semiconductor N, N'-dioctyl-3,4:9,10-perylene tetracarboxylic diimide (PTCDI-C 8) by surface X-ray crystallography. We show that PTCDI-C 8 forms smooth layered films on Al 2O 3 (11-20) with an outstanding degree of molecular order. The thin-film structure is found to consist of a triclinic unit cell with the plane of the aromatic core tilted by 67 +/- 2 degrees with respect to the surface plane, which differs significantly from the bulk structure. The 3D crystallites extend with vertical coherent order across the entire film thickness 
650 4 |a Journal Article 
700 1 |a Barrena, Esther  |e verfasserin  |4 aut 
700 1 |a Zhang, Xue N  |e verfasserin  |4 aut 
700 1 |a de Oteyza, Dimas G  |e verfasserin  |4 aut 
700 1 |a Major, János  |e verfasserin  |4 aut 
700 1 |a Dehm, Volker  |e verfasserin  |4 aut 
700 1 |a Würthner, Frank  |e verfasserin  |4 aut 
700 1 |a Cavalcanti, Leide P  |e verfasserin  |4 aut 
700 1 |a Dosch, Helmut  |e verfasserin  |4 aut 
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