The reaction of mixtures of [Rh4(CO)12] and triphenylphosphite with carbon monoxide or syngas as studied by high-resolution, high-pressure NMR spectroscopy

The fragmentation and redistribution reactions of [Rh4(CO)12-x{P(OPh)3}x] (x = 1-4) with carbon monoxide have been studied using high-resolution, high-pressure NMR spectroscopy. Under the conditions of efficient gas mixing in a high-pressure NMR bubble column, [Rh4(CO)9{P(OPh)3}3] fragments to give...

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Publié dans:	Magnetic resonance in chemistry : MRC. - 1985. - 46 Suppl 1(2008) vom: 15., Seite S100-6
Auteur principal:	Overend, Gillian (Auteur)
Autres auteurs:	Iggo, Jonathan A, Heaton, Brian T, Whyman, Robin
Format:	Article en ligne
Langue:	English
Publié:	2008
Accès à la collection:	Magnetic resonance in chemistry : MRC
Sujets:	Journal Article Research Support, Non-U.S. Gov't Organometallic Compounds Phosphites Carbon Monoxide 7U1EE4V452 Rhodium DMK383DSAC