The impact of tripodal chelates on water exchange kinetics and mechanisms : a variable temperature and pressure 17O NMR study to clarify the structure-reactivity relationship in [Fe(II)(L)(H2O2](-) complexes
The effect of temperature and pressure on the water exchange reaction of [Fe(II)(NTA)(H2O)2](-) and [Fe(II)(BADA)(H2O)2](-) (NTA = nitrilotriacetate; BADA = beta-alanindiacetate) was studied by 17O NMR spectroscopy. The [Fe(II)(NTA)(H2O)2](-) complex showed a water exchange rate constant, k(ex), of...
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