NMR studies on the novel heterobimetallic complexes [M(dppm)(Ph(2)PCH(2)PPh(2)PPPP) {Pt(PPh3)2}]OTf (M = Rh, Ir) derived from the stepwise activation of white phosphorus

The solution structures of the novel heterobimetallic complexes [Ir(dppm)(Ph(2)PCH(2)PPh(2)PPPP){Pt(PPh(3))2}]OTf and [Rh(dppm)(Ph(2)PCH(2)PPh(2)PPPP){Pt(PPh(3))(2)}]OTf derived from the reaction of Rh and Ir--P(5) precursors with [Pt(C2H4)(PPh3)2] have been unambiguously assigned on the basis of 1H...

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Publié dans:Magnetic resonance in chemistry : MRC. - 1985. - 46 Suppl 1(2008) vom: 15., Seite S120-5
Auteur principal: Caporali, Maria (Auteur)
Autres auteurs: Barbaro, Pierluigi, Bolaño, Sandra, Gonsalvi, Luca, Carpio, Sonia Mañas, Peruzzini, Maurizio
Format: Article en ligne
Langue:English
Publié: 2008
Accès à la collection:Magnetic resonance in chemistry : MRC
Sujets:Journal Article Research Support, Non-U.S. Gov't Ligands Organometallic Compounds Organophosphorus Compounds Phosphorus 27YLU75U4W Iridium 44448S9773 Rhodium DMK383DSAC