Detection of platinum dihydride bisphosphine complexes and studies of their reactivity through para-hydrogen-enhanced NMR methods
In-situ NMR studies on the reactions of Pt{CH2 = CHSi(Me)2}2O)(PCy3) with phosphines, HSiEt3 and--hydrogen or Pt(L)(L')(Me)(2) alone enable the detection of cis-Pt(L)(L')(H)2 [L = PCy3 and L' = PCy2H, PPh3 or PCy3] which then undergo hydride site interchange and H2 reductive eliminati...
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Détails bibliographiques
| Publié dans: | Magnetic resonance in chemistry : MRC. - 1985. - 46 Suppl 1(2008) vom: 15., Seite S107-14
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| Auteur principal: |
Godard, Cyril
(Auteur) |
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| Autres auteurs: |
López-Serrano, Joaquín,
Gálvez-López, María-Dolores,
Roselló-Merino, Marta,
Duckett, Simon B,
Khazal, Iman,
Lledós, Agustí,
Whitwood, Adrian C |
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| Format: | Article en ligne
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| Langue: | English |
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| Publié: |
2008
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| Accès à la collection: | Magnetic resonance in chemistry : MRC
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| Sujets: | Journal Article
Research Support, Non-U.S. Gov't
Phosphines
Platinum Compounds
Hydrogen
7YNJ3PO35Z |
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