Detection of platinum dihydride bisphosphine complexes and studies of their reactivity through para-hydrogen-enhanced NMR methods

Detection of platinum dihydride bisphosphine complexes and studies of their reactivity through para-hydrogen-enhanced NMR methods

In-situ NMR studies on the reactions of Pt{CH2 = CHSi(Me)2}2O)(PCy3) with phosphines, HSiEt3 and--hydrogen or Pt(L)(L')(Me)(2) alone enable the detection of cis-Pt(L)(L')(H)2 [L = PCy3 and L' = PCy2H, PPh3 or PCy3] which then undergo hydride site interchange and H2 reductive eliminati...

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Veröffentlicht in:Magnetic resonance in chemistry : MRC. - 1985. - 46 Suppl 1(2008) vom: 15., Seite S107-14
1. Verfasser: Godard, Cyril (VerfasserIn)
Weitere Verfasser: López-Serrano, Joaquín, Gálvez-López, María-Dolores, Roselló-Merino, Marta, Duckett, Simon B, Khazal, Iman, Lledós, Agustí, Whitwood, Adrian C
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2008
Zugriff auf das übergeordnete Werk:Magnetic resonance in chemistry : MRC
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Phosphines Platinum Compounds Hydrogen 7YNJ3PO35Z
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700 1 |a López-Serrano, Joaquín  |e verfasserin  |4 aut 
700 1 |a Gálvez-López, María-Dolores  |e verfasserin  |4 aut 
700 1 |a Roselló-Merino, Marta  |e verfasserin  |4 aut 
700 1 |a Duckett, Simon B  |e verfasserin  |4 aut 
700 1 |a Khazal, Iman  |e verfasserin  |4 aut 
700 1 |a Lledós, Agustí  |e verfasserin  |4 aut 
700 1 |a Whitwood, Adrian C  |e verfasserin  |4 aut 
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