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231223s2008 xx |||||o 00| ||eng c |
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|a 10.1021/la801443y
|2 doi
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|a eng
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1 |
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|a Tencer, Michal
|e verfasserin
|4 aut
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|a Toposelective electrochemical desorption of thiol SAMs from neighboring polycrystalline gold surfaces
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|c 2008
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 01.12.2008
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|a Date Revised 30.10.2008
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a We describe a method for the selective desorption of thiol self-assembled monolayers from gold surfaces having micrometer-scale separations on a substrate. In an electrolyte solution, the electrical resistance between the adjacent areas can be much lower than the resistance between a surface and the counter electrode. Also, both reductive and oxidative thiol desorption may occur. Therefore, the potentials of the surfaces must be independently controlled with a multichannel potentiostat and operating windows for a given thiol/electrolyte system must be established. In this study operating windows were established for 1-dodecanethiol-based SAMs in phosphate buffer, phosphate-buffered saline, and sodium hydroxide solution, and selective SAM removal was successfully performed in a four-electrode configuration
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|a Journal Article
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|a Sulfhydryl Compounds
|2 NLM
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|a Gold
|2 NLM
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|a 7440-57-5
|2 NLM
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| 700 |
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|a Berini, Pierre
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 24(2008), 21 vom: 04. Nov., Seite 12097-101
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|g volume:24
|g year:2008
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|g month:11
|g pages:12097-101
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|u http://dx.doi.org/10.1021/la801443y
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