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231223s2008 xx |||||o 00| ||eng c |
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|a 10.1021/la801945q
|2 doi
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|a pubmed24n0609.xml
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|a (DE-627)NLM182669572
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|a (NLM)18817420
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|a DE-627
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|e rakwb
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|a eng
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|a Wolff, Max
|e verfasserin
|4 aut
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|a Shear induced relaxation of polymer micelles at the solid-liquid interface
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|c 2008
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 13.11.2008
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|a Date Revised 16.10.2008
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a A 20% aqueous solution of (ethylene oxide) 99-(propylene oxide) 65-(ethylene oxide) 99, F127, was investigated by combining rheology in a cone/plate-geometry and surface-sensitive grazing incident neutron scattering. The crystalline structure formed by the polymer micelles becomes less pronounced for low shear rates, but correlations increase for higher shear rates. After stopping shear a slow relaxation of the micelles is found in the vicinity (50 mum thick layer) of a hydrophilic silicon wall (strong micelle-wall interaction), while a fast relaxation is observed in the boundary layer against the hydrophobic silicon wall (weak micelle-wall interaction). The results show that in the vicinity of the interface wall-particle interactions compete heavily with the shear force acting on the liquid
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|a Journal Article
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|a Steitz, Roland
|e verfasserin
|4 aut
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|a Gutfreund, Philipp
|e verfasserin
|4 aut
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|a Voss, Nicole
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Gerth, Stefan
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Walz, Marco
|e verfasserin
|4 aut
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| 700 |
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|a Magerl, Andreas
|e verfasserin
|4 aut
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| 700 |
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|a Zabel, Hartmut
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 24(2008), 20 vom: 21. Okt., Seite 11331-3
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:24
|g year:2008
|g number:20
|g day:21
|g month:10
|g pages:11331-3
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|u http://dx.doi.org/10.1021/la801945q
|3 Volltext
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