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231223s2008 xx |||||o 00| ||eng c |
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|a 10.1021/la8011052
|2 doi
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|a eng
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|a Deng, Xingyi
|e verfasserin
|4 aut
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|a Surface chemistry of Cu in the presence of CO2 and H2O
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|c 2008
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|a Text
|b txt
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 13.11.2008
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|a Date Revised 29.08.2008
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a The chemical nature of copper and copper oxide (Cu 2O) surfaces in the presence of CO 2 and H 2O at room temperature was investigated using ambient pressure X-ray photoelectron spectroscopy. The studies reveal that in the presence of 0.1 torr CO 2 several species form on the initially clean Cu, including carbonate CO 3 (2) (-), CO 2 (delta-) and C (0), while no modifications occur on an oxidized surface. The addition of 0.1 ML Zn to the Cu results in the complete conversion of CO 2 (delta-) to carbonate. In a mixture of 0.1 torr H 2O and 0.1 torr CO 2, new species are formed, including hydroxyl, formate and methoxy, with H 2O providing the hydrogen needed for the formation of hydrogenated species
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|a Journal Article
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|a Verdaguer, Albert
|e verfasserin
|4 aut
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|a Herranz, Tirma
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Weis, Christoph
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Bluhm, Hendrik
|e verfasserin
|4 aut
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| 700 |
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|a Salmeron, Miquel
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1991
|g 24(2008), 17 vom: 02. Sept., Seite 9474-8
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|g year:2008
|g number:17
|g day:02
|g month:09
|g pages:9474-8
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