Switchable photoluminescence of CdTe nanocrystals by temperature-responsive microgels

In the present study, we report a method for preparing a fluorescent thermosensitive hybrid material based on monodisperse, thermosensitive poly( N-isopropyl acrylamide) (PNIPAM) microgels covered with CdTe nanocrystals of 3.2 nm diameter. The CdTe nanocrystals were covalently immobilized on the sur...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 24(2008), 17 vom: 02. Sept., Seite 9820-4
1. Verfasser: Agrawal, M (VerfasserIn)
Weitere Verfasser: Rubio-Retama, J, Zafeiropoulos, N E, Gaponik, N, Gupta, S, Cimrova, V, Lesnyak, V, López-Cabarcos, E, Tzavalas, S, Rojas-Reyna, R, Eychmüller, A, Stamm, M
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2008
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Acrylic Resins Amines Cadmium Compounds Gels Ions Polymers poly-N-isopropylacrylamide 25189-55-3 mehr... Tellurium NQA0O090ZJ cadmium telluride STG188WO13
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245 1 0 |a Switchable photoluminescence of CdTe nanocrystals by temperature-responsive microgels 
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520 |a In the present study, we report a method for preparing a fluorescent thermosensitive hybrid material based on monodisperse, thermosensitive poly( N-isopropyl acrylamide) (PNIPAM) microgels covered with CdTe nanocrystals of 3.2 nm diameter. The CdTe nanocrystals were covalently immobilized on the surface of PNIPAM microgels. The chemical environment around the CdTe nanocrystals was modified by changing the temperature and inducing the microgel volume-phase transition. This change provoked a steep variation in the nanocrystal photoluminescence (PL) intensity in such a way that when the temperature was under the low critical solution temperature (LCST) of the polymer (36 degrees C) the PL of the nanocrystals was strongly quenched, whereas above the LCST the PL intensity was restored 
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700 1 |a Rubio-Retama, J  |e verfasserin  |4 aut 
700 1 |a Zafeiropoulos, N E  |e verfasserin  |4 aut 
700 1 |a Gaponik, N  |e verfasserin  |4 aut 
700 1 |a Gupta, S  |e verfasserin  |4 aut 
700 1 |a Cimrova, V  |e verfasserin  |4 aut 
700 1 |a Lesnyak, V  |e verfasserin  |4 aut 
700 1 |a López-Cabarcos, E  |e verfasserin  |4 aut 
700 1 |a Tzavalas, S  |e verfasserin  |4 aut 
700 1 |a Rojas-Reyna, R  |e verfasserin  |4 aut 
700 1 |a Eychmüller, A  |e verfasserin  |4 aut 
700 1 |a Stamm, M  |e verfasserin  |4 aut 
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