Templated synthesis of mesolamellar n-alkylamine borophosphates

A family of lamellar mesostructured n-alkylamine borophosphates, denoted C n A-BPO (BPO stands for inorganic borophosphate layer; n = 9-15, the number of carbon atoms in the n-alkylamine chain) has been prepared hydrothermally at 160 degrees C by using neutral n-alkylamines as templates. Those C n A...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 24(2008), 17 vom: 02. Sept., Seite 9323-7
1. Verfasser: Chen, Shuang (VerfasserIn)
Weitere Verfasser: Borrmann, Horst, Huang, Ya-Xi, Zhang, Zhi-Jun, Chen, Hao-Hong, Zhao, Jing-Tai
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2008
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a A family of lamellar mesostructured n-alkylamine borophosphates, denoted C n A-BPO (BPO stands for inorganic borophosphate layer; n = 9-15, the number of carbon atoms in the n-alkylamine chain) has been prepared hydrothermally at 160 degrees C by using neutral n-alkylamines as templates. Those C n A-BPO compounds were characterized by powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric measurements, and differential thermal analysis (TG-DTA) as well as chemical analyses. Interestingly, these compounds may form a bilayer, a monolayer, or mixed state of bilayer and monolayer structures depending on the content of n-alkylamine. Linear relationships for both bilayer and monolayer compounds were observed between the interlayer distances and the numbers of carbon atoms in the n-alkylamine chain. The thickness of the inorganic layers, the arrangement of n-alkylamine in the interlayer space, and the composition of the compounds are proposed 
650 4 |a Journal Article 
700 1 |a Borrmann, Horst  |e verfasserin  |4 aut 
700 1 |a Huang, Ya-Xi  |e verfasserin  |4 aut 
700 1 |a Zhang, Zhi-Jun  |e verfasserin  |4 aut 
700 1 |a Chen, Hao-Hong  |e verfasserin  |4 aut 
700 1 |a Zhao, Jing-Tai  |e verfasserin  |4 aut 
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