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231223s2008 xx |||||o 00| ||eng c |
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|a 10.1021/la800462u
|2 doi
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|a pubmed24n0603.xml
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|a (DE-627)NLM180840568
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|a (NLM)18620436
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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1 |
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|a Yang, Menglong
|e verfasserin
|4 aut
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|a One-step photochemical attachment of NHS-terminated monolayers onto silicon surfaces and subsequent functionalization
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|c 2008
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 08.09.2008
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|a Date Revised 21.11.2013
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a N-Hydroxysuccinimide (NHS)-ester-terminated monolayers were covalently attached in one step onto silicon using visible light. This mild photochemical attachment, starting from omega-NHS-functionalized 1-alkenes, yields a clean and flat monolayer-modified silicon surface and allows a mild and rapid functionalization of the surface by substitution of the NHS-ester moieties with amines at room temperature. Using a combination of analytical techniques (infrared reflection absorption spectroscopy (IRRAS), extensive X-ray photoelectron spectroscopy (XPS) in combination with density functional theory calculations of the XPS chemical shifts of the carbon atoms, atomic force microscopy (AFM), and static contact angle measurements), it was shown that the NHS-ester groups were attached fully intact onto the surface. The surface reactivity of the NHS-ester moieties toward amines was qualitatively and quantitatively evaluated via the reaction with para-trifluoromethyl benzylamine and biotin hydrazide
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Esters
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|a Succinimides
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|a biotin hydrazide
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|a 66640-86-6
|2 NLM
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|a Biotin
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|a 6SO6U10H04
|2 NLM
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|a N-hydroxysuccinimide
|2 NLM
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|a MJE3791M4T
|2 NLM
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|a Silicon
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|a Z4152N8IUI
|2 NLM
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|a Teeuwen, Rosalie L M
|e verfasserin
|4 aut
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|a Giesbers, Marcel
|e verfasserin
|4 aut
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|a Baggerman, Jacob
|e verfasserin
|4 aut
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|a Arafat, Ahmed
|e verfasserin
|4 aut
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|a de Wolf, Frits A
|e verfasserin
|4 aut
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|a van Hest, Jan C M
|e verfasserin
|4 aut
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|a Zuilhof, Han
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 24(2008), 15 vom: 05. Aug., Seite 7931-8
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:24
|g year:2008
|g number:15
|g day:05
|g month:08
|g pages:7931-8
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|u http://dx.doi.org/10.1021/la800462u
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