Magnetic nanorods confined in a lamellar lyotropic phase

The dilute lamellar phase of the nonionic surfactant C 12EO 5 was doped with goethite (iron oxide) nanorods up to a fraction of 5 vol %. The interaction between the inclusions and the host phase was studied by polarized optical microscopy (with or without an applied magnetic field) and by small-angl...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 24(2008), 15 vom: 05. Aug., Seite 8205-9
1. Verfasser: Béneut, Keevin (VerfasserIn)
Weitere Verfasser: Constantin, Doru, Davidson, Patrick, Dessombz, Arnaud, Chanéac, Corinne
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2008
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a The dilute lamellar phase of the nonionic surfactant C 12EO 5 was doped with goethite (iron oxide) nanorods up to a fraction of 5 vol %. The interaction between the inclusions and the host phase was studied by polarized optical microscopy (with or without an applied magnetic field) and by small-angle X-ray scattering. We find that, when the orientation of the nanorods is modified using the magnetic field, the texture of the lamellar phase changes accordingly; one can thus induce a homeotropic-planar reorientation transition. On the other hand, the lamellar phase induces an attractive interaction between the nanorods. In more concentrated lamellar phases (under stronger confinement) the particles form aggregates. This behavior is not encountered for a similar system doped with spherical particles, emphasizing the role of particle shape in the interaction between doping particles and the host phase 
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700 1 |a Constantin, Doru  |e verfasserin  |4 aut 
700 1 |a Davidson, Patrick  |e verfasserin  |4 aut 
700 1 |a Dessombz, Arnaud  |e verfasserin  |4 aut 
700 1 |a Chanéac, Corinne  |e verfasserin  |4 aut 
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