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20231223155602.0 |
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231223s2008 xx ||||| 00| ||eng c |
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|a pubmed24n0602.xml
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|a (DE-627)NLM180497847
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|a (NLM)18584055
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
1 |
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|a Anderson, Donde R
|e verfasserin
|4 aut
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| 245 |
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|a Kinetic Selectivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)Carbenes
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| 264 |
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|c 2008
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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| 338 |
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|a Band
|b nc
|2 rdacarrier
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| 500 |
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|a Date Revised 20.10.2021
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a The evaluation of ruthenium olefin metathesis catalysts 4-6 bearing cyclic (alkyl)(amino)carbenes (CAACs) in the cross-metathesis of cis-1,4-diacetoxy-2-butene (7) with allylbenzene (8) and the ethenolysis of methyl oleate (11) is reported. Relative to most NHC-substituted complexes, CAAC-substituted catalysts exhibit lower E/Z ratios (3:1 at 70% conversion) in the cross-metathesis of 7 and 8. Additionally, complexes 4-6 demonstrate good selectivity for the formation of terminal olefins versus internal olefins in the ethenolysis of 11. Indeed, complex 6 achieved 35 000 TONs, the highest recorded to date. CAAC-substituted complexes exhibit markedly different kinetic selectivity than most NHC-substituted complexes
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| 650 |
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|a Journal Article
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1 |
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|a Ung, Thay
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Mkrtumyan, Garik
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Bertrand, Guy
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Grubbs, Robert H
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Schrodi, Yann
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Organometallics
|d 1998
|g 27(2008), 4 vom: 12. Jan., Seite 563-566
|w (DE-627)NLM098167103
|x 0276-7333
|7 nnns
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| 773 |
1 |
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|g volume:27
|g year:2008
|g number:4
|g day:12
|g month:01
|g pages:563-566
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|a GBV_USEFLAG_A
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| 912 |
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|a SYSFLAG_A
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| 912 |
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|a GBV_NLM
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| 912 |
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|a GBV_ILN_350
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| 951 |
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|a AR
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| 952 |
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|d 27
|j 2008
|e 4
|b 12
|c 01
|h 563-566
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