Facile preparation of self-assembled hydrogel-like GdPO4*H2O nanorods

Of the methods employed in the preparation of one-dimensional lanthanide phosphate (LnPO(4)) nanorods/nanowires, such as GdPO(4), the hydrothermal method has been mainly used as a synthetic route. In this study, we report a facile low-temperature solution approach to prepare GdPO 4*H(2)O nanorods by...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 24(2008), 15 vom: 05. Aug., Seite 8309-13
1. Verfasser: Huang, Chih-Chia (VerfasserIn)
Weitere Verfasser: Lo, Yi-Wei, Kuo, Wen-Shuo, Hwu, Jih-Ru, Su, Wu-Chou, Shieh, Dar-Bin, Yeh, Chen-Sheng
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2008
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Phosphates Hydrogel, Polyethylene Glycol Dimethacrylate 25852-47-5 Gadolinium AU0V1LM3JT
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520 |a Of the methods employed in the preparation of one-dimensional lanthanide phosphate (LnPO(4)) nanorods/nanowires, such as GdPO(4), the hydrothermal method has been mainly used as a synthetic route. In this study, we report a facile low-temperature solution approach to prepare GdPO 4*H(2)O nanorods by simply refluxing GdCl(3) and KH(2)PO(4) for only 15 min at 88 degrees C, an approach that can easily be scaled up by increasing the reagent amounts. We observed a highly viscous macroscopic hydrogel-like material when we mixed as-prepared GdPO(4)*H(2)O nanomaterials with H(2)O. Hydrogels are an important class of biomaterials. Their building blocks, normally formed from protein-, peptide-, polymer-, and lipid-based materials, offer three-dimensional scaffolds for drug delivery, tissue engineering, and biosensors. Our preliminary results showed that GdPO(4)*H(2)O hydrogels could be used for encapsulation and drug release, and that they were biocompatible, acting as scaffolds to foster cell proliferation. These findings suggested that they might have biomedical uses. Our findings may lead to the creation of other inorganic nanomaterial-based hydrogels apart from the organic and biomolecular protein-, peptide-, polymer-, and lipid-based building blocks 
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650 7 |a Hydrogel, Polyethylene Glycol Dimethacrylate  |2 NLM 
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650 7 |a Gadolinium  |2 NLM 
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700 1 |a Lo, Yi-Wei  |e verfasserin  |4 aut 
700 1 |a Kuo, Wen-Shuo  |e verfasserin  |4 aut 
700 1 |a Hwu, Jih-Ru  |e verfasserin  |4 aut 
700 1 |a Su, Wu-Chou  |e verfasserin  |4 aut 
700 1 |a Shieh, Dar-Bin  |e verfasserin  |4 aut 
700 1 |a Yeh, Chen-Sheng  |e verfasserin  |4 aut 
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