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231223s2008 xx |||||o 00| ||eng c |
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|a 10.1021/la800304r
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|a eng
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|a Marmur, Abraham
|e verfasserin
|4 aut
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|a From hygrophilic to superhygrophobic
|b theoretical conditions for making high-contact-angle surfaces from low-contact-angle materials
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|c 2008
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|a Text
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|a ƒaComputermedien
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|a Date Completed 15.08.2008
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|a Date Revised 08.07.2008
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a The possibility of making high-contact-angle, rough surfaces from low-contact-angle materials has recently been suggested and demonstrated. A thermodynamic analysis of this possibility in terms of feasibility and stability is presented. It turns out that only roughness topographies that conform to a feasibility condition which is developed in the present paper can support this phenomenon. Even under conditions that support the phenomenon, the high-contact-angle state may not be stable, and transition from the heterogeneous (Cassie-Baxter) wetting regime to the homogeneous (Wenzel) regime with a lower contact angle may occur. In addition, it is suggested to use the general terms hygrophilic and hygrophobic (based on the Greek prefix hygro- that means liquid) to describe low- and high-contact-angle surfaces, respectively
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|a Journal Article
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|t Langmuir : the ACS journal of surfaces and colloids
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