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231223s2008 xx |||||o 00| ||eng c |
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|a 10.1021/la800528m
|2 doi
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|a pubmed24n0600.xml
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|a eng
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|a South, Clinton R
|e verfasserin
|4 aut
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|a Bridged coordination polymer multilayers with tunable properties
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|c 2008
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 15.08.2008
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|a Date Revised 15.11.2012
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Coordination multilayers consisting of Pd(II) pincer-type complexes and poly(vinyl pyridine) were synthesized and characterized. Film properties were found to be dependent on and could be tuned by varying bath deposition concentrations, polymer molecular weight, and solution additives that compete with binding. Generally, smoother, thinner films were obtained with lower poly(vinyl pyridine) deposition bath concentrations. Likewise, film thickness and roughness could be reduced by employing a higher-molecular-weight poly(vinyl pyridine). Film properties could also be influenced by using acetonitrile as a solution additive, effectively driving the binding equilibrium slightly toward the free species
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Research Support, U.S. Gov't, Non-P.H.S.
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|a Ligands
|2 NLM
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|a Polyvinyls
|2 NLM
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|a Pyridines
|2 NLM
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|a pyridine
|2 NLM
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| 650 |
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|a NH9L3PP67S
|2 NLM
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| 700 |
1 |
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|a Weck, Marcus
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 24(2008), 14 vom: 15. Juli, Seite 7506-11
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|x 1520-5827
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|g volume:24
|g year:2008
|g number:14
|g day:15
|g month:07
|g pages:7506-11
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|u http://dx.doi.org/10.1021/la800528m
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