Structure elucidation and complete NMR spectral assignments of two new dammarane-type tetraglycosides from Panax quinquefolium

Copyright (c) 2008 John Wiley & Sons, Ltd.

Bibliographische Detailangaben
Veröffentlicht in:Magnetic resonance in chemistry : MRC. - 1985. - 46(2008), 8 vom: 13. Aug., Seite 786-90
1. Verfasser: Jiang, Hai-Ping (VerfasserIn)
Weitere Verfasser: Qiu, Ying-Kun, Cheng, Da-Ren, Kang, Ting-Guo, Dou, De-Qiang
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2008
Zugriff auf das übergeordnete Werk:Magnetic resonance in chemistry : MRC
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Glycosides Triterpenes
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520 |a Two new saponins were isolated from leaves of Panax quinquefolium and their structures were elucidated as 3beta, 12beta, 20S-trihydroxy-25-methoxydammar-23-ene 3-O-{[beta-D-glucopyranosyl(1-->2)-beta-D-glucopyranosyl]-20-O-[alpha-L-arabinopyranosyl(1-->6)]-beta-D-glucopyranoside (1) and 3beta, 20S-dihydroxy-12beta, 23R-epoxydammar-24-ene 3-O-{[beta-D-glucopyranosyl(1-->2)-beta-D-glucopyranosyl]-20-O-[beta-D-xylopyanosyl(1-->6)]-beta-D-glucopyranoside (2) on the basis of (1)D and (2)D NMR (including (1)H, (13)C-NMR, (1)H-(1)H COSY, HSQC, TOCSY, HMBC, and NOESY), ESI-MS spectrometry and chemical methods 
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