Giant micelles of organoplatinum(II) gemini amphiphiles

Organoplatinum(II) gemini amphiphiles with two different chain lengths are synthesized and characterized. Self-assembly at the air-water interface is investigated as a function of chain length and reduction in surface area by using Langmuir-trough techniques. The Langmuir-trough experiments lead to...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1999. - 24(2008), 10 vom: 20. Mai, Seite 5400-10
1. Verfasser: Maran, Umamageswaran (VerfasserIn)
Weitere Verfasser: Conley, Hiram, Frank, Markus, Arif, Atta M, Orendt, Anita M, Britt, David, Hlady, Vladimir, Davis, Robert, Stang, Peter J
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2008
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, N.I.H., Extramural Research Support, U.S. Gov't, Non-P.H.S. Micelles Platinum Compounds Quinones Water 059QF0KO0R Platinum 49DFR088MY
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520 |a Organoplatinum(II) gemini amphiphiles with two different chain lengths are synthesized and characterized. Self-assembly at the air-water interface is investigated as a function of chain length and reduction in surface area by using Langmuir-trough techniques. The Langmuir-trough experiments lead to a conjecture that surface aggregates may be the adsorbing units. Atomic force microscopy on the transferred Langmuir-Schaefer films reveals spontaneous formation of wormlike micellar aggregates. A shear-induced transition and alignment are proposed for the observed effects 
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650 4 |a Research Support, N.I.H., Extramural 
650 4 |a Research Support, U.S. Gov't, Non-P.H.S. 
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700 1 |a Conley, Hiram  |e verfasserin  |4 aut 
700 1 |a Frank, Markus  |e verfasserin  |4 aut 
700 1 |a Arif, Atta M  |e verfasserin  |4 aut 
700 1 |a Orendt, Anita M  |e verfasserin  |4 aut 
700 1 |a Britt, David  |e verfasserin  |4 aut 
700 1 |a Hlady, Vladimir  |e verfasserin  |4 aut 
700 1 |a Davis, Robert  |e verfasserin  |4 aut 
700 1 |a Stang, Peter J  |e verfasserin  |4 aut 
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