Shape- and size-dependent refractive index sensitivity of gold nanoparticles

Gold nanoparticles of different shapes and sizes, including nanospheres, nanocubes, nanobranches, nanorods, and nanobipyramids, were dispersed into water-glycerol mixtures of varying volume ratios to investigate the response of their surface plasmon peaks to the refractive index of the surrounding m...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 24(2008), 10 vom: 20. Mai, Seite 5233-7
1. Verfasser: Chen, Huanjun (VerfasserIn)
Weitere Verfasser: Kou, Xiaoshan, Yang, Zhi, Ni, Weihai, Wang, Jianfang
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2008
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Gold nanoparticles of different shapes and sizes, including nanospheres, nanocubes, nanobranches, nanorods, and nanobipyramids, were dispersed into water-glycerol mixtures of varying volume ratios to investigate the response of their surface plasmon peaks to the refractive index of the surrounding medium. The refractive index sensitivities and figures of merit were found to be dependent on both the shape and the size of the Au nanoparticles. The index sensitivities generally increase as Au nanoparticles become elongated and their apexes become sharper. Au nanospheres exhibit the smallest refractive index sensitivity of 44 nm/RIU and Au nanobranches exhibit the largest index sensitivity of 703 nm/RIU. Au nanobipyramids possess the largest figures of merit, which increase from 1.7 to 4.5 as the aspect ratio is increased from 1.5 to 4.7 
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700 1 |a Kou, Xiaoshan  |e verfasserin  |4 aut 
700 1 |a Yang, Zhi  |e verfasserin  |4 aut 
700 1 |a Ni, Weihai  |e verfasserin  |4 aut 
700 1 |a Wang, Jianfang  |e verfasserin  |4 aut 
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