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231223s2008 xx |||||o 00| ||eng c |
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7 |
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|a 10.1021/la703672u
|2 doi
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|a pubmed24n0593.xml
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|a (DE-627)NLM177801891
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|a (NLM)18294019
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|a DE-627
|b ger
|c DE-627
|e rakwb
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| 041 |
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|a eng
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| 100 |
1 |
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|a Peng, Junxia
|e verfasserin
|4 aut
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| 245 |
1 |
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|a New dicholesteryl-based gelators
|b chirality and spacer length effect
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| 264 |
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|c 2008
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| 336 |
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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| 338 |
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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| 500 |
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|a Date Completed 05.05.2008
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|a Date Revised 21.11.2013
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Eight new diacid amides of dicholesteryl L(D)-alaninates were designed and prepared. The compounds with spacers containing three, four, five, or six carbon atoms and L-alanine residues are denoted as 1a, 2a, 3a, and 4a, respectively, and those containing D-alanine residues are denoted as 1b, 2b, 3b, and 4b, respectively. A gelation test revealed that a subtle change in the length of the spacer and an inverse in the chirality of the amino acid residue can produce a dramatic change in the gelation behavior of the compounds and the microstructures of the gels, as revealed by SEM, XRD, and CD measurements. Importantly, for the compounds 1 and 2, those containing d-alanine residues (1b, 2b) are more efficient gelators than their analogues with opposite chirality (1a, 2a). For the compounds of longer spacers (3, 4), however, those containing l-alanine residues (3a, 4a) are superior to the corresponding ones with d-alanine residues (3b, 4b). Very interestingly, of the 139 gel systems studied, at least 11 of them gel spontaneously at room temperature. Studies of the rheological properties of the example systems of these gels demonstrated that change in the spacer lengths of the gelators has a great effect upon the mechanical properties of the corresponding gels, and the studies also revealed the thixotropic properties of the gels. Furthermore, it was observed that 4a forms water-in-oil gel emulsions with some organic solvents by simple agitating the systems at room temperature
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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| 650 |
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|a Amides
|2 NLM
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| 650 |
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|a Cholesterol Esters
|2 NLM
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| 650 |
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7 |
|a Gels
|2 NLM
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| 650 |
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|a Alanine
|2 NLM
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| 650 |
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7 |
|a OF5P57N2ZX
|2 NLM
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| 700 |
1 |
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|a Liu, Kaiqiang
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Liu, Jing
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhang, Qiuhong
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Feng, Xuli
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Fang, Yu
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 24(2008), 7 vom: 01. Apr., Seite 2992-3000
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:24
|g year:2008
|g number:7
|g day:01
|g month:04
|g pages:2992-3000
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| 856 |
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|u http://dx.doi.org/10.1021/la703672u
|3 Volltext
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