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231223s2008 xx |||||o 00| ||eng c |
| 024 |
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|a 10.1021/la7028824
|2 doi
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|a pubmed25n0589.xml
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|a (NLM)18186657
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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1 |
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|a Vanderah, David J
|e verfasserin
|4 aut
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|a Self-assembled monolayers of an oligo(ethylene oxide) disulfide and its corresponding thiol assembled from water
|b characterization and protein resistance
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|c 2008
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 02.04.2008
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|a Date Revised 16.11.2017
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Self-assembled monolayers (SAMs) of the disulfide [S(CH2CH2O)6CH3]2 ([S(EO)6]2) on Au from 95% ethanol and from 100% water are described. Spectroscopic ellipsometry and reflection-absorption infrared spectroscopy indicate that the [S(EO)6]2 films are similar to the disordered films of HS(CH2CH2O)6CH3 ((EO)6) and HS(CH2)3O(CH2CH2O)5CH3 (C3EO5) at their protein adsorption minima. The [S(EO)6]2 SAMs exhibit constant film thickness (d) of 1.2 +/- 0.2 nm over long immersion times (up to 20 days) and do not attain the highly ordered, 7/2 helical structure of the (EO)6 and C3EO5 SAMs (d = 2.0 nm). Exposure of these self-limiting [S(EO)6]2 SAMs to bovine serum albumin show high resistance to protein adsorption
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|a Journal Article
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|a Research Support, U.S. Gov't, Non-P.H.S.
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|a Biocompatible Materials
|2 NLM
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|a Proteins
|2 NLM
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|a Sulfhydryl Compounds
|2 NLM
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|a Water
|2 NLM
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|a 059QF0KO0R
|2 NLM
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|a Serum Albumin, Bovine
|2 NLM
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|a 27432CM55Q
|2 NLM
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|a Ethylene Oxide
|2 NLM
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|a JJH7GNN18P
|2 NLM
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|a Walker, Marlon L
|e verfasserin
|4 aut
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|a Rocco, Mark A
|e verfasserin
|4 aut
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| 700 |
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|a Rubinson, Kenneth A
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1985
|g 24(2008), 3 vom: 05. Feb., Seite 826-9
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnas
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| 773 |
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|g volume:24
|g year:2008
|g number:3
|g day:05
|g month:02
|g pages:826-9
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|u http://dx.doi.org/10.1021/la7028824
|3 Volltext
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