17O NMR investigation of phosphite hydrolysis mechanisms
Copyright (c) 2007 John Wiley & Sons, Ltd.
| Publié dans: | Magnetic resonance in chemistry : MRC. - 1985. - 45(2007), 12 vom: 01. Dez., Seite 1022-6 |
|---|---|
| Auteur principal: | |
| Autres auteurs: | |
| Format: | Article |
| Langue: | English |
| Publié: |
2007
|
| Accès à la collection: | Magnetic resonance in chemistry : MRC |
| Sujets: | Journal Article Research Support, Non-U.S. Gov't Oxygen Isotopes Phosphites Solutions |
| Résumé: | Copyright (c) 2007 John Wiley & Sons, Ltd. The use of solution 17O NMR spectroscopy in verifying the mechanism of trialkyl phosphite hydrolysis is presented. Trimethyl phosphite was reacted with 17O-labeled H2O at different temperatures and two reactant concentrations, with the reaction being monitored by 17O NMR. Kinetic details elucidated from the NMR spectra are also discussed |
|---|---|
| Description: | Date Completed 05.02.2008 Date Revised 06.12.2007 published: Print Citation Status MEDLINE |
| ISSN: | 1097-458X |