Processing of copper converter slag for metal reclamation. Part I : Extraction and recovery of copper and cobalt

Clean processing of copper converter slag to reclaim cobalt and copper could be a challenge. An innovative and environmentally sound approach for recovering valuable metals from such a slag has been developed in the present study. Curing the slag with strong sulphuric acid, without re-smelting or ro...

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Veröffentlicht in:Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA. - 1991. - 25(2007), 5 vom: 10. Okt., Seite 440-8
1. Verfasser: Deng, Tong (VerfasserIn)
Weitere Verfasser: Ling, Yunhan
Format: Aufsatz
Sprache:English
Veröffentlicht: 2007
Zugriff auf das übergeordnete Werk:Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Barium Compounds Industrial Waste Sulfides Sulfuric Acids Cobalt 3G0H8C9362 Manganese 42Z2K6ZL8P mehr... Silicon Dioxide 7631-86-9 Copper 789U1901C5 sulfuric acid O40UQP6WCF barium sulfide TV3U2GEW4H
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245 1 0 |a Processing of copper converter slag for metal reclamation. Part I  |b Extraction and recovery of copper and cobalt 
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520 |a Clean processing of copper converter slag to reclaim cobalt and copper could be a challenge. An innovative and environmentally sound approach for recovering valuable metals from such a slag has been developed in the present study. Curing the slag with strong sulphuric acid, without re-smelting or roasting as practiced currently in the industry, render it accessible to leaching, and more than 95% of cobalt and up to 90% of copper was extracted together with iron by water leaching, leaving silica behind in a residue. The copper in the leach liquor was recovered by cementation with iron and the dissolved iron crystallized as ferrous sulphate monohydrate. The cobalt in the mother-liquor rich in iron was recovered by either cementation or sulphide precipitation. Operation variables in the new process were also investigated and optimized 
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