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231223s2007 xx ||||| 00| ||eng c |
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|a (DE-627)NLM174620942
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|a (NLM)17960944
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
1 |
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|a Kilcher, Giona
|e verfasserin
|4 aut
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|a Emulsion macromonomer cross-linking. A preparative method for oxidation-responsive nanoparticles with a controlled network structure
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|c 2007
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|a Band
|b nc
|2 rdacarrier
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|a Date Completed 08.02.2008
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|a Date Revised 27.10.2021
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a We here report on a preparative, template-based method for oxidation-responsive, poly(propylene sulfide) cross-linked nanoparticles. In this study we demonstrate that preformed, narrow polydispersity, and end-functional polysulfides can be dispersed to yield stable emulsions, which can then be converted into stable nanoparticles through photochemically initiated cross-linking. The nanoparticle size is substantially templated on that of the precursor emulsions; the nanoparticles bulk is an elastomeric material with a homogeneous cross-linking density. The nanoparticles show a peculiar, two-stage behavior upon exposure to oxidants, which is likely composed of a first agglomeration phase followed by swelling
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Cross-Linking Reagents
|2 NLM
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|a Elastomers
|2 NLM
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|a Emulsions
|2 NLM
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|a Oxidants
|2 NLM
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|a Polymers
|2 NLM
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|a Sulfides
|2 NLM
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|a poly(propylene sulfide)
|2 NLM
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|a Duckham, Craig
|e verfasserin
|4 aut
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|a Tirelli, Nicola
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 23(2007), 24 vom: 20. Nov., Seite 12309-17
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:23
|g year:2007
|g number:24
|g day:20
|g month:11
|g pages:12309-17
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