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|a eng
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| 100 |
1 |
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|a Cantin, Sophie
|e verfasserin
|4 aut
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| 245 |
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|a Spontaneous polymerization at the air-water interface
|b a Brewster angle microscopy study
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|c 2007
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|a Band
|b nc
|2 rdacarrier
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|a Date Completed 08.02.2008
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|a Date Revised 13.11.2007
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a When a dioctadecyldimethylammonium bromide (DODA) monolayer is spread onto a styrene sulfonate (SSt) aqueous solution, this monomer undergoes a spontaneous polymerization process [Fichet, O; Teyssié, D. Macromolecules 2002, 35, 5352]. However, the polymer synthesized in this monolayer cannot be investigated by classical characterization techniques. Brewster angle microscopy has thus been used as a complementary method in order to study this spontaneous polymerization. From these measurements, the threshold concentration above which the spontaneous polymerization occurs has been determined more precisely; the monomer adsorption under the DODA monolayer has been evidenced as being very fast, as supposed previously; moreover, sodium bicarbonate is confirmed as an inhibitor of the polymerization. Also, the replacement of SSt by toluene sulfonate (TSt) confirms the SSt spontaneous polymerization. Finally, the molecular weight and/or the structure of the polymer synthesized in the monolayer seems to be different from those synthesized in solution
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|a Journal Article
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|a Fichet, Odile
|e verfasserin
|4 aut
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1 |
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|a Perrot, Françoise
|e verfasserin
|4 aut
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| 700 |
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|a Teyssié, Dominique
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 23(2007), 24 vom: 20. Nov., Seite 12243-8
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|g year:2007
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|g month:11
|g pages:12243-8
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