Direct observation of the unstable intermediates in radical addition reaction by using an interfacing microchip combined with an NMR
(c) 2007 John Wiley & Sons, Ltd.
| Veröffentlicht in: | Magnetic resonance in chemistry : MRC. - 1985. - 45(2007), 11 vom: 15. Nov., Seite 989-92 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , , |
| Format: | Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2007
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| Zugriff auf das übergeordnete Werk: | Magnetic resonance in chemistry : MRC |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Boranes Oximes Protons Boron N9E3X5056Q triethylborane Z3S980Z4P3 |
| Zusammenfassung: | (c) 2007 John Wiley & Sons, Ltd. Direct observation of the unstable intermediate in the radical addition reaction of the oxime ether 1 mediated by triethylborane (Et(3)B) is described using (1)H and (11)B micro channeled cell for synthesis monitoring (MICCS), which was recently developed as an interfacing microchip for NMR. It was possible that the signal of the intermediate was observed as a result of using MICCS technique with a standard NMR instrument. This result supports the structure of the intermediate analyzed by diffusion-ordered spectroscopy (DOSY) NMR method in a previous paper. The procedure of micro channeled cell for synthesis monitoring-nuclear magnetic resonance (MICCS-NMR) was much easier than that of DOSY method. It was proven that it could be applied to the reaction in an anhydrous condition |
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| Beschreibung: | Date Completed 06.12.2007 Date Revised 16.11.2017 published: Print Citation Status MEDLINE |
| ISSN: | 1097-458X |