Inclusion complex of spironaphthoxazine with gamma-cyclodextrin and its photochromism study
An environmentally benign transparent photochromic film, 1,3-dihydro-1,3,3-trimethylspiro[2H-indole-2,3'-[3H]-naphtho[2,1-b][1,4]oxazine] (SPO) /gamma-cyclodextrin (gamma-CD), was prepared using the cast-coating method, and the nanocavity effect of gamma-CD on the photochromism of SPO was studi...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 23(2007), 18 vom: 28. Aug., Seite 9443-6 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , |
| Format: | Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2007
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | An environmentally benign transparent photochromic film, 1,3-dihydro-1,3,3-trimethylspiro[2H-indole-2,3'-[3H]-naphtho[2,1-b][1,4]oxazine] (SPO) /gamma-cyclodextrin (gamma-CD), was prepared using the cast-coating method, and the nanocavity effect of gamma-CD on the photochromism of SPO was studied. The film mainly consists of the inclusion complex SPOgamma-CD, which has been verified by EA, TGA, XRD, MS, and ICD to comprise a 1:1 host-guest stoichiometry. The film shows normal photochromism. The decoloration of photomerocyanine (PMC) fits biexponential decay: PMCs located in the cavity of gamma-CD decay with a rate constant of 6.0 x 10(-2) s(-1), which is nearly one order faster than those PMCs outside of the cavity |
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| Beschreibung: | Date Completed 02.10.2007 Date Revised 21.08.2007 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |