Water-soluble anionic POSS-core dendrimer : synthesis and copper(II) complexes in aqueous solution
A carboxylic acid-terminated polyhedral oligosilsesquioxane (POSS)-core dendrimer (POSS-CO2H) was synthesized from octa(3-ammoniumpropyl)octasilsesquioxane octachloride (POSS-NH3+) via a t-butyl ester-terminated POSS-core dendrimer that was prepared from neutralized POSS-NH3+ and t-butyl acrylate. C...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1991. - 23(2007), 17 vom: 14. Aug., Seite 9057-63 |
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| Weitere Verfasser: | , , |
| Format: | Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2007
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | A carboxylic acid-terminated polyhedral oligosilsesquioxane (POSS)-core dendrimer (POSS-CO2H) was synthesized from octa(3-ammoniumpropyl)octasilsesquioxane octachloride (POSS-NH3+) via a t-butyl ester-terminated POSS-core dendrimer that was prepared from neutralized POSS-NH3+ and t-butyl acrylate. Complexing properties of the sodium salts of POSS-CO2H (POSS-CO2Na) with Cu2+ were studied in comparison with those of the G1.5 poly(amidoamine) (PAMAM) dendrimer (G1.5-CO2Na) by spectroscopic approach and isothermal titration calorimetry. In the case of G1.5-CO2Na, Cu2+-N4 and Cu2+-N2O2 complexes are possible coordination modes, and only a Cu2+-N2O2 complex can be formed for POSS-CO2Na. In the case of POSS-CO2Na, upon increasing the concentration of Cu2+, the values of the binding constants decreased. However, the values of binding constants in the regions of the Cu2+-N2O2 coordination mode for G1.5-CO2Na increased with increasing concentration of Cu2+. This observation suggests that the uptake of Cu2+ is inhibited by increasing binding numbers of Cu2+ due to the rigid structure of the POSS-core dendrimer |
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| Beschreibung: | Date Completed 17.09.2007 Date Revised 08.08.2007 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 0743-7463 |