Effect of copper(II) on natural organic matter removal during drinking water coagulation using aluminum-based coagulants

Coagulation has been proposed as a best available technology for controlling natural organic matter (NOM) during drinking water treatment. The presence of heavy metals such as copper(II) in source water, which may form copper-NOM complexes and/or interact with a coagulant, may pose a potential chall...

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Veröffentlicht in:Water environment research : a research publication of the Water Environment Federation. - 1998. - 79(2007), 6 vom: 28. Juni, Seite 593-9
1. Verfasser: Liu, Guojing (VerfasserIn)
Weitere Verfasser: Zhang, Xiangru, Talley, Jeffrey W
Format: Aufsatz
Sprache:English
Veröffentlicht: 2007
Zugriff auf das übergeordnete Werk:Water environment research : a research publication of the Water Environment Federation
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S. Alum Compounds Aluminum Compounds Chlorides Organic Chemicals Water Pollutants, Chemical Water 059QF0KO0R mehr... aluminum sulfate 34S289N54E Aluminum Chloride 3CYT62D3GA Copper 789U1901C5
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520 |a Coagulation has been proposed as a best available technology for controlling natural organic matter (NOM) during drinking water treatment. The presence of heavy metals such as copper(II) in source water, which may form copper-NOM complexes and/or interact with a coagulant, may pose a potential challenge on the coagulation of NOM. In this work, the effect of copper(II) on NOM removal by coagulation using alum or PAX-18 (a commercial polymerized aluminum chloride from Kemiron Inc., Bartow, Florida) was examined. The results show that the presence of 1 to 10 mg/L of copper(H) in the simulated waters improved the total organic carbon (TOC) removal by up to 25% for alum coagulation and by up to 22% for PAX-18 coagulation. The increased NOM removal with the presence of copper(II) in the waters can most likely be ascribed to the formation copper-NOM complexes that may be more adsorbable on aluminum precipitates and to the formation of copper(II) co-precipitates that may also adsorb NOM. The presence of 1 to 5 mg/L of copper(I) in the waters containing 3 mg/L NOM as carbon was reduced below the maximum contaminant level goal (1.3 mg/L as copper) using either coagulant. The results suggest that the presence of copper(H) in source water may not adversely affect the NOM removal by coagulation. A good linear correlation was observed between the TOC removal efficiency and the log-total moles of the precipitated metals, which include the metal ion from a coagulant and the divalent metal ion(s) in source water 
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650 7 |a Aluminum Compounds  |2 NLM 
650 7 |a Chlorides  |2 NLM 
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650 7 |a Copper  |2 NLM 
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700 1 |a Zhang, Xiangru  |e verfasserin  |4 aut 
700 1 |a Talley, Jeffrey W  |e verfasserin  |4 aut 
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