Controlling the electrophoretic mobility of single-walled carbon nanotubes : a comparison of theory and experiment

The electrophoretic mobilities of single-walled carbon nanotubes (SWNTs) in agarose gels subjected to negatively charged covalent functionalization and noncovalent anionic surfactant adsorption are compared using a simplified hydrodynamic model. Net charges are calculated on the basis of estimated f...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1991. - 23(2007), 14 vom: 03. Juli, Seite 7768-76
1. Verfasser: Usrey, Monica L (VerfasserIn)
Weitere Verfasser: Nair, Nitish, Agnew, Daniel E, Pina, Cesar F, Strano, Michael S
Format: Aufsatz
Sprache:English
Veröffentlicht: 2007
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Comparative Study Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S. 4-hydroxybenzene diazonium Anions Cations Diazonium Compounds Nanotubes, Carbon Phenols mehr... Surface-Active Agents Polyethylene Glycols 3WJQ0SDW1A Sodium 9NEZ333N27 Sodium Cholate NU3Y4CCH8Z
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520 |a The electrophoretic mobilities of single-walled carbon nanotubes (SWNTs) in agarose gels subjected to negatively charged covalent functionalization and noncovalent anionic surfactant adsorption are compared using a simplified hydrodynamic model. Net charges are calculated on the basis of estimated friction coefficients for cylindrical rodlike particles. The effects of functionalization with negatively charged 4-hydroxybenzene diazonium and anionic sodium cholate are quantified and compared with model predictions. The adsorption of Na+ counterions into the nonionic surfactant layer adsorbed on SWNTs (Triton-X-405) is shown to induce a positive charge and reverse the mobility under select conditions. This effect has not been identified or quantified for nanoparticle systems and may be important in the processing of these systems 
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650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 4 |a Research Support, U.S. Gov't, Non-P.H.S. 
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700 1 |a Nair, Nitish  |e verfasserin  |4 aut 
700 1 |a Agnew, Daniel E  |e verfasserin  |4 aut 
700 1 |a Pina, Cesar F  |e verfasserin  |4 aut 
700 1 |a Strano, Michael S  |e verfasserin  |4 aut 
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