Surface-initiated, ring-opening metathesis polymerization : formation of diblock copolymer brushes and solvent-dependent morphological changes

In this article, we report the formation of diblock copolymer brushes on a gold surface by surface-initiated, ring-opening metathesis polymerization (SI-ROMP) with the newly developed ruthenium catalyst [(H2IMes)(3-Br-py)2(Cl)2Ru=CHPh]. Taking advantage of the highly improved activity of the rutheni...

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Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1991. - 23(2007), 12 vom: 05. Juni, Seite 6761-5
1. Verfasser: Kong, Bokyung (VerfasserIn)
Weitere Verfasser: Lee, Jungkyu K, Choi, Insung S
Format: Aufsatz
Sprache:English
Veröffentlicht: 2007
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't 5-norbornene-2,3-dimethanol Esters Norbornanes Polymers Ruthenium 7UI0TKC3U5