Spontaneous formation of micrometer-size inorganic peapods

We show that polyoxometalate (ammonium phosphomolybdate) Keggin in aqueous dispersions upon sonication spontaneously transforms into micrometer-sized, peapod-shaped structures. The formation of these peapods is preceded by the generation of spherical aggregates. The particles have been characterized...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 23(2007), 10 vom: 08. Mai, Seite 5292-5
1. Verfasser: Roy, Soumyajit (VerfasserIn)
Weitere Verfasser: Rijneveld-Ockers, Maria T, Groenewold, Jan, Kuipers, Bonny W M, Meeldijk, Hans, Kegel, Willem K
Format: Aufsatz
Sprache:English
Veröffentlicht: 2007
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a We show that polyoxometalate (ammonium phosphomolybdate) Keggin in aqueous dispersions upon sonication spontaneously transforms into micrometer-sized, peapod-shaped structures. The formation of these peapods is preceded by the generation of spherical aggregates. The particles have been characterized experimentally by time-resolved dynamic light scattering (DLS), transmission electron microscopy (TEM), and scanning TEM with a high-angle annular dark field detector (STEM-HAADF) for energy-dispersive X-ray (STEM/EDX) elemental analyses. A pathway for the phenomenon is proposed 
650 4 |a Journal Article 
700 1 |a Rijneveld-Ockers, Maria T  |e verfasserin  |4 aut 
700 1 |a Groenewold, Jan  |e verfasserin  |4 aut 
700 1 |a Kuipers, Bonny W M  |e verfasserin  |4 aut 
700 1 |a Meeldijk, Hans  |e verfasserin  |4 aut 
700 1 |a Kegel, Willem K  |e verfasserin  |4 aut 
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