1H and 13C NMR assignments for two anthraquinones and two xanthones from the mangrove fungus (ZSUH-36)

Copyright (c) 2007 John Wiley & Sons, Ltd.

Bibliographische Detailangaben
Veröffentlicht in:Magnetic resonance in chemistry : MRC. - 1985. - 45(2007), 5 vom: 01. Mai, Seite 434-8
1. Verfasser: Shao, Changlun (VerfasserIn)
Weitere Verfasser: She, Zhigang, Guo, Zhiyong, Peng, Hong, Cai, Xiaoling, Zhou, Shining, Gu, Yucheng, Lin, Yongcheng
Format: Aufsatz
Sprache:English
Veröffentlicht: 2007
Zugriff auf das übergeordnete Werk:Magnetic resonance in chemistry : MRC
Schlagworte:Journal Article 6,8-di-O-methyl versiconol Anthraquinones Carbon Isotopes Protons Xanthones aversin OCJ5M677TN
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520 |a We report the unambiguous assignments of the (1)H and (13)C NMR spectra of one new natural product, namely, 6,8-di-O-methyl versiconol (1) together with one known anthraquinone aversin (2) and two xanthones 5-methoxysterigmatocystin (3) and sterigmatocystin (4). These compounds were all isolated from the mangrove endophytic fungus ZSUH-36 from the South China Sea. 1D and 2D NMR experiments including COSY, HMQC and HMBC were used to elucidate the structures. Variations in the (1)H NMR spectrum of 6,8-di-O-methyl versiconol (1) were also observed in the temperature range 25-75 degrees C. In addition, the plausible biogenetic path from 1 to 2 is discussed 
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700 1 |a She, Zhigang  |e verfasserin  |4 aut 
700 1 |a Guo, Zhiyong  |e verfasserin  |4 aut 
700 1 |a Peng, Hong  |e verfasserin  |4 aut 
700 1 |a Cai, Xiaoling  |e verfasserin  |4 aut 
700 1 |a Zhou, Shining  |e verfasserin  |4 aut 
700 1 |a Gu, Yucheng  |e verfasserin  |4 aut 
700 1 |a Lin, Yongcheng  |e verfasserin  |4 aut 
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