Unambiguous NMR spectral assignments of salvinorin A

The complete assignments of the (1)H and (13)C NMR spectra of the hallucinogenic neoclerodane diterpenoid salvinorin A were determined in three different NMR solvents using HSQC, HMBC and COSY. Solvent systems are described that allow the resolution of all (1)H signals. Virtual coupling was observed...

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Veröffentlicht in:Magnetic resonance in chemistry : MRC. - 1985. - 45(2007), 4 vom: 01. Apr., Seite 351-4
1. Verfasser: Giner, José-Luis (VerfasserIn)
Weitere Verfasser: Kiemle, David J, Kutrzeba, Lukasz, Zjawiony, Jordan
Format: Aufsatz
Sprache:English
Veröffentlicht: 2007
Zugriff auf das übergeordnete Werk:Magnetic resonance in chemistry : MRC
Schlagworte:Journal Article Research Support, N.I.H., Extramural Diterpenes Diterpenes, Clerodane Hallucinogens salvinorin A T56W91NG6J
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500 |a CommentIn: Magn Reson Chem. 2007 Sep;45(9):801. - PMID 17638315 
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520 |a The complete assignments of the (1)H and (13)C NMR spectra of the hallucinogenic neoclerodane diterpenoid salvinorin A were determined in three different NMR solvents using HSQC, HMBC and COSY. Solvent systems are described that allow the resolution of all (1)H signals. Virtual coupling was observed for the protons at C-2, C-3 and C-4 in the 600 MHz (1)H spectrum in CDCl(3). The complete assignments of the (1)H and (13)C NMR spectra of salvinorin B are also reported 
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