Determination of the surface coverage of exfoliated carbon nanotubes by surfactant molecules in aqueous solution

To determine the surface coverage of exfoliated carbon nanotubes by surfactant molecules, we propose four experimental methods based on thermogravimetric analysis, UV-vis spectroscopy, surface tension measurements, and a variant of Maron's titration. We apply all four methods to aqueous mixture...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 23(2007), 7 vom: 27. März, Seite 3646-53
1. Verfasser: Grossiord, Nadia (VerfasserIn)
Weitere Verfasser: Schoot, Paul van der, Meuldijk, Jan, Koning, Cor E
Format: Aufsatz
Sprache:English
Veröffentlicht: 2007
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a To determine the surface coverage of exfoliated carbon nanotubes by surfactant molecules, we propose four experimental methods based on thermogravimetric analysis, UV-vis spectroscopy, surface tension measurements, and a variant of Maron's titration. We apply all four methods to aqueous mixtures of carbon nanotubes and the surfactant sodium dodecyl sulfate and consistently find a surface coverage of between 1.5 and 2 g of surfactant per gram of carbon nanotubes. This corresponds to slightly more than two SDS molecules per square nanometer, which is comparable to the known maximum packing density of SDS at the air-water interface 
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700 1 |a Schoot, Paul van der  |e verfasserin  |4 aut 
700 1 |a Meuldijk, Jan  |e verfasserin  |4 aut 
700 1 |a Koning, Cor E  |e verfasserin  |4 aut 
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