Effectiveness of zerovalent iron and nickel catalysts for degrading chlorinated solvents and n-nitrosodimethylamine in natural groundwater

Laboratory batch experiments were performed to evaluate the effectiveness of nickel catalysts, nanoscale zerovalent iron (nZVI) doped with palladium, and microscale ZVI for treatment of tetrachloroethene, trichloroethene, and n-nitrosodimethylamine (NDMA) in soil-groundwater slurries. Results indica...

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Veröffentlicht in:Water environment research : a research publication of the Water Environment Federation. - 1998. - 79(2007), 1 vom: 18. Jan., Seite 57-62
1. Verfasser: Schaefer, Charles E (VerfasserIn)
Weitere Verfasser: Topoleski, Corinne, Fuller, Mark E
Format: Aufsatz
Sprache:English
Veröffentlicht: 2007
Zugriff auf das übergeordnete Werk:Water environment research : a research publication of the Water Environment Federation
Schlagworte:Evaluation Study Journal Article Nitrosamines Soil Pollutants Solvents Water Pollutants, Chemical Trichloroethylene 290YE8AR51 Nickel 7OV03QG267 mehr... Iron E1UOL152H7 Dimethylnitrosamine M43H21IO8R Tetrachloroethylene TJ904HH8SN
Beschreibung
Zusammenfassung:Laboratory batch experiments were performed to evaluate the effectiveness of nickel catalysts, nanoscale zerovalent iron (nZVI) doped with palladium, and microscale ZVI for treatment of tetrachloroethene, trichloroethene, and n-nitrosodimethylamine (NDMA) in soil-groundwater slurries. Results indicated that the presence of NDMA inhibited degradation of chlorinated solvents. Although both the nickel catalyst and nZVI were able to degrade NDMA in deionized water, neither of these metals was effective at degrading NDMA in the soil-groundwater system evaluated in this study. The effectiveness of the nickel catalyst and nZVI, with respect to treatment of the chlorinated solvents, also appeared to be highly dependent on the groundwater geochemical conditions. Overall results of this study suggest that the degradation mechanisms involving nickel catalysts and nZVI in natural soil/groundwater systems are not well-understood, and addition of metal catalysts to ZVI may not necessarily enhance observed degradation rates in natural systems
Beschreibung:Date Completed 03.04.2007
Date Revised 10.12.2019
published: Print
Citation Status MEDLINE
ISSN:1554-7531