Argon adsorption on Cu3(benzene-1,3,5-tricarboxylate)2(H2O)3 metal-organic framework

Using volumetric adsorption techniques, we have measured the adsorption of argon on Cu3(BTC)2(H2O)3, (BTC = benzene-1,3,5-tricarboxylate), a microporous metal-organic framework structure, at temperatures between 66 and 143 K. In addition to the experiments, we have used Grand Canonical Monte Carlo s...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 23(2007), 6 vom: 13. März, Seite 3106-9
1. Verfasser: Krungleviciute, V (VerfasserIn)
Weitere Verfasser: Lask, K, Heroux, L, Migone, A D, Lee, J-Y, Li, J, Skoulidas, A
Format: Aufsatz
Sprache:English
Veröffentlicht: 2007
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Using volumetric adsorption techniques, we have measured the adsorption of argon on Cu3(BTC)2(H2O)3, (BTC = benzene-1,3,5-tricarboxylate), a microporous metal-organic framework structure, at temperatures between 66 and 143 K. In addition to the experiments, we have used Grand Canonical Monte Carlo simulations to calculate the adsorption isotherm of argon at 87 K. Our experimental and theoretical results are compared to those of previous studies. The experiments were performed using a high density of points, allowing us to obtain, in detail, the isosteric heat's coverage dependence. Our values from the simulations are in reasonable agreement with those obtained in the experiments 
650 4 |a Journal Article 
700 1 |a Lask, K  |e verfasserin  |4 aut 
700 1 |a Heroux, L  |e verfasserin  |4 aut 
700 1 |a Migone, A D  |e verfasserin  |4 aut 
700 1 |a Lee, J-Y  |e verfasserin  |4 aut 
700 1 |a Li, J  |e verfasserin  |4 aut 
700 1 |a Skoulidas, A  |e verfasserin  |4 aut 
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