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231223s2007 xx ||||| 00| ||eng c |
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|e rakwb
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|a eng
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1 |
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|a Hashidzume, Akihito
|e verfasserin
|4 aut
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| 245 |
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|a Cooperative binding of nonionic surfactant to hydrophobically modified polyanions as studied by frontal analysis continuous capillary electrophoresis
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| 264 |
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|c 2007
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|a Band
|b nc
|2 rdacarrier
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|a Date Completed 02.05.2007
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|a Date Revised 06.02.2007
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a The binding of a nonionic surfactant, Triton X-100 (TX), to amphiphilic copolymers of sodium 2-(acrylamido)-2-methylpropanesulfonate and N-dodecylmethacrylamide (C12) (p(A/C12(x)), where x denotes the mol % content of C12) was investigated by frontal analysis continuous capillary electrophoresis (FACCE) combined with dynamic light scattering focusing on the effect of the hydrophobe content on the binding in a wide range of x (5-60 mol %). From binding isotherms obtained from FACCE data, the binding was found to be cooperative in the whole range of x. Furthermore, a significant change in the binding behavior, i.e., cooperativity, was found to occur in a relatively narrow range of x (38-50 mol %), which is attributable to a change in the self-association behavior of p(A/C12(x)) in this x range
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|a Journal Article
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|a Watanabe, Shin-ichi
|e verfasserin
|4 aut
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|a Morishima, Yotaro
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 23(2007), 4 vom: 13. Feb., Seite 2191-7
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:23
|g year:2007
|g number:4
|g day:13
|g month:02
|g pages:2191-7
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| 952 |
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|d 23
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|h 2191-7
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