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|a eng
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|a Balu, Caroline
|e verfasserin
|4 aut
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|a Colloidal phase separation of concentrated PNIPAm solutions
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|c 2007
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|a Text
|b txt
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|a ohne Hilfsmittel zu benutzen
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|2 rdamedia
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|a Date Completed 27.06.2007
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|a Date Revised 20.02.2007
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a In the concentration range of 1-6 wt %, solutions of a thermosensitive polymer (poly-N-isopropylacrylamide (PNIPAm), Mw = 1.4 x 10(5) g.mol(-1)) are shown to phase separate in the form of dense stable colloids of nearly pure polymer. Diffuse wave spectroscopy and small-angle neutron scattering both provide consistent measurements of the colloidal size as a function of temperature. Results are in agreement with a Cahn regime of spinodal decomposition blocked at an early stage, prior to a growth that would lead to a macroscopic phase separation. [Early results of this work were presented at the 231st American Chemical Society National Meeting, Symposium on Amphiphilic Polymers, Atlanta, GA, 2006, March 26-30.]
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|a Journal Article
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|a Delsanti, Michel
|e verfasserin
|4 aut
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|a Guenoun, Patrick
|e verfasserin
|4 aut
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|a Monti, Fabrice
|e verfasserin
|4 aut
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|a Cloitre, Michel
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1991
|g 23(2007), 5 vom: 27. Feb., Seite 2404-7
|w (DE-627)NLM098181009
|x 0743-7463
|7 nnns
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|g year:2007
|g number:5
|g day:27
|g month:02
|g pages:2404-7
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