Natural-abundance 15N--13C correlation spectra of vitamin B-12

Copyright (c) 2007 John Wiley & Sons, Ltd.

Bibliographische Detailangaben
Veröffentlicht in:Magnetic resonance in chemistry : MRC. - 1985. - 45(2007), 2 vom: 12. Feb., Seite 103-5
1. Verfasser: Kupce, Eriks (VerfasserIn)
Weitere Verfasser: Freeman, Ray
Format: Aufsatz
Sprache:English
Veröffentlicht: 2007
Zugriff auf das übergeordnete Werk:Magnetic resonance in chemistry : MRC
Schlagworte:Journal Article Carbon Isotopes Nitrogen Isotopes Vitamin B 12 P6YC3EG204
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520 |a Two-dimensional nitrogen-carbon NMR correlation spectra have been derived by a new reconstruction technique based on standard two-dimensional HMQC and HMBC spectra, and operating with natural 15N and 13C isotopic abundances. Compared with conventional three-dimensional spectroscopy in which 15N and 13C spins must be present in the same molecule, the reconstruction method offers two orders of magnitude improvement in sensitivity. Vitamin B-12 serves as an illustrative example 
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