1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenanthroline

1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenanthroline

Copyright (c) 2006 John Wiley & Sons, Ltd.

Bibliographische Detailangaben
Veröffentlicht in:Magnetic resonance in chemistry : MRC. - 1985. - 45(2007), 1 vom: 15. Jan., Seite 24-36
1. Verfasser: Pazderski, Leszek (VerfasserIn)
Weitere Verfasser: Tousek, Jaromír, Sitkowski, Jerzy, Kozerski, Lech, Marek, Radek, Szłyk, Edward
Format: Aufsatz
Sprache:English
Veröffentlicht: 2007
Zugriff auf das übergeordnete Werk:Magnetic resonance in chemistry : MRC
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Carbon Isotopes Nitrogen Isotopes Organogold Compounds Phenanthrolines Cobalt 3G0H8C9362 2,2'-Dipyridyl 551W113ZEP mehr... Gold 7440-57-5 Hydrogen 7YNJ3PO35Z Rhodium DMK383DSAC cobaltous chloride EVS87XF13W 1,10-phenanthroline W4X6ZO7939
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245 1 0 |a 1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenanthroline 
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520 |a Au(III), Co(III) and Rh(III) chloride complexes with pyridine (py), 2,2'-bipyridine (bpy) and 1,10-phenanthroline (phen) of the general formulae [M1LCl3], trans-[M2L4Cl2]+, mer-[M2L3Cl3], [M1(LL)Cl2]+, cis-[M2(LL)2Cl2]+, where M1=Au; M2=Co, Rh; L=py; LL=bpy, phen, were studied by 1H--13C HMBC and 1H--15N HMQC/HSQC. The 1H, 13C and 15N coordination shifts (the latter from ca-78 to ca-107 ppm) are discussed in relation to the type of metal, electron configuration, coordination sphere geometry and the type of ligand. The 13C and 15N chemical shifts were also calculated by quantum-chemical NMR methods, which reproduced well the experimental tendencies concerning the coordination sphere geometry and the ligand type 
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650 7 |a Rhodium  |2 NLM 
650 7 |a DMK383DSAC  |2 NLM 
650 7 |a cobaltous chloride  |2 NLM 
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700 1 |a Tousek, Jaromír  |e verfasserin  |4 aut 
700 1 |a Sitkowski, Jerzy  |e verfasserin  |4 aut 
700 1 |a Kozerski, Lech  |e verfasserin  |4 aut 
700 1 |a Marek, Radek  |e verfasserin  |4 aut 
700 1 |a Szłyk, Edward  |e verfasserin  |4 aut 
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