|
|
|
|
LEADER |
01000caa a22002652 4500 |
001 |
NLM166053856 |
003 |
DE-627 |
005 |
20250207171307.0 |
007 |
tu |
008 |
231223s2007 xx ||||| 00| ||eng c |
028 |
5 |
2 |
|a pubmed25n0554.xml
|
035 |
|
|
|a (DE-627)NLM166053856
|
035 |
|
|
|a (NLM)17048265
|
040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
041 |
|
|
|a eng
|
100 |
1 |
|
|a Pazderski, Leszek
|e verfasserin
|4 aut
|
245 |
1 |
0 |
|a 1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenanthroline
|
264 |
|
1 |
|c 2007
|
336 |
|
|
|a Text
|b txt
|2 rdacontent
|
337 |
|
|
|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
|
338 |
|
|
|a Band
|b nc
|2 rdacarrier
|
500 |
|
|
|a Date Completed 05.03.2007
|
500 |
|
|
|a Date Revised 19.11.2015
|
500 |
|
|
|a published: Print
|
500 |
|
|
|a Citation Status MEDLINE
|
520 |
|
|
|a Copyright (c) 2006 John Wiley & Sons, Ltd.
|
520 |
|
|
|a Au(III), Co(III) and Rh(III) chloride complexes with pyridine (py), 2,2'-bipyridine (bpy) and 1,10-phenanthroline (phen) of the general formulae [M1LCl3], trans-[M2L4Cl2]+, mer-[M2L3Cl3], [M1(LL)Cl2]+, cis-[M2(LL)2Cl2]+, where M1=Au; M2=Co, Rh; L=py; LL=bpy, phen, were studied by 1H--13C HMBC and 1H--15N HMQC/HSQC. The 1H, 13C and 15N coordination shifts (the latter from ca-78 to ca-107 ppm) are discussed in relation to the type of metal, electron configuration, coordination sphere geometry and the type of ligand. The 13C and 15N chemical shifts were also calculated by quantum-chemical NMR methods, which reproduced well the experimental tendencies concerning the coordination sphere geometry and the ligand type
|
650 |
|
4 |
|a Journal Article
|
650 |
|
4 |
|a Research Support, Non-U.S. Gov't
|
650 |
|
7 |
|a Carbon Isotopes
|2 NLM
|
650 |
|
7 |
|a Nitrogen Isotopes
|2 NLM
|
650 |
|
7 |
|a Organogold Compounds
|2 NLM
|
650 |
|
7 |
|a Phenanthrolines
|2 NLM
|
650 |
|
7 |
|a Cobalt
|2 NLM
|
650 |
|
7 |
|a 3G0H8C9362
|2 NLM
|
650 |
|
7 |
|a 2,2'-Dipyridyl
|2 NLM
|
650 |
|
7 |
|a 551W113ZEP
|2 NLM
|
650 |
|
7 |
|a Gold
|2 NLM
|
650 |
|
7 |
|a 7440-57-5
|2 NLM
|
650 |
|
7 |
|a Hydrogen
|2 NLM
|
650 |
|
7 |
|a 7YNJ3PO35Z
|2 NLM
|
650 |
|
7 |
|a Rhodium
|2 NLM
|
650 |
|
7 |
|a DMK383DSAC
|2 NLM
|
650 |
|
7 |
|a cobaltous chloride
|2 NLM
|
650 |
|
7 |
|a EVS87XF13W
|2 NLM
|
650 |
|
7 |
|a 1,10-phenanthroline
|2 NLM
|
650 |
|
7 |
|a W4X6ZO7939
|2 NLM
|
700 |
1 |
|
|a Tousek, Jaromír
|e verfasserin
|4 aut
|
700 |
1 |
|
|a Sitkowski, Jerzy
|e verfasserin
|4 aut
|
700 |
1 |
|
|a Kozerski, Lech
|e verfasserin
|4 aut
|
700 |
1 |
|
|a Marek, Radek
|e verfasserin
|4 aut
|
700 |
1 |
|
|a Szłyk, Edward
|e verfasserin
|4 aut
|
773 |
0 |
8 |
|i Enthalten in
|t Magnetic resonance in chemistry : MRC
|d 1985
|g 45(2007), 1 vom: 15. Jan., Seite 24-36
|w (DE-627)NLM098179667
|x 0749-1581
|7 nnns
|
773 |
1 |
8 |
|g volume:45
|g year:2007
|g number:1
|g day:15
|g month:01
|g pages:24-36
|
912 |
|
|
|a GBV_USEFLAG_A
|
912 |
|
|
|a SYSFLAG_A
|
912 |
|
|
|a GBV_NLM
|
912 |
|
|
|a GBV_ILN_350
|
951 |
|
|
|a AR
|
952 |
|
|
|d 45
|j 2007
|e 1
|b 15
|c 01
|h 24-36
|