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231223s2006 xx ||||| 00| ||eng c |
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|a pubmed24n0552.xml
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|a (DE-627)NLM165423366
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|a (NLM)16981754
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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1 |
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|a Fulghum, Timothy M
|e verfasserin
|4 aut
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| 245 |
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|a Fuzzy ternary particle systems by surface-initiated atom transfer radical polymerization from layer-by-layer colloidal core-shell macroinitiator particles
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|c 2006
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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| 338 |
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|a Band
|b nc
|2 rdacarrier
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| 500 |
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|a Date Completed 11.09.2007
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|a Date Revised 19.09.2006
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a We report the synthesis of ternary polymer particle material systems composed of (a) a spherical colloidal particle core, coated with (b) a polyelectrolyte intermediate shell, and followed by (c) a grafted polymer brush prepared by surface-initiated polymerization as the outer shell. The layer-by-layer (LbL) deposition process was utilized to create a functional intermediate shell of poly(diallyl-dimethylammonium chloride)/poly(acrylic acid) multilayers on the colloid template with the final layer containing an atom transfer radical polymerization (ATRP) macroinitiator polyelectrolyte. The intermediate core-shell architecture was analyzed with FT-IR, electrophoretic mobililty (zeta-potential) measurements, atomic force microscopy, and transmission electron microscopy (TEM) techniques. The particles were then utilized as macroinitiators for the surface-initiated ATRP grafting process for poly(methyl methacrylate) polymer brush. The polymer grafting was confirmed with thermo gravimetric analysis, FT-IR, and TEM. The polymer brush formed the outermost shell for a ternary colloidal particle system. By combining the LbL and surface-initiated ATRP methods to produce controllable multidomain core-shell architectures, interesting functional properties should be obtainable based on independent polyelectrolyte and polymer brush behavior
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|a Journal Article
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|a Patton, Derek L
|e verfasserin
|4 aut
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|a Advincula, Rigoberto C
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 22(2006), 20 vom: 26. Sept., Seite 8397-402
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:22
|g year:2006
|g number:20
|g day:26
|g month:09
|g pages:8397-402
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|a GBV_ILN_721
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|a AR
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|d 22
|j 2006
|e 20
|b 26
|c 09
|h 8397-402
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