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231223s2006 xx ||||| 00| ||eng c |
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|a DE-627
|b ger
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|e rakwb
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|a eng
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| 100 |
1 |
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|a Men, Yongfeng
|e verfasserin
|4 aut
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|a Non-affine structural evolution of soft colloidal crystalline latex films under stretching as observed via synchrotron X-ray scattering
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|c 2006
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|a Band
|b nc
|2 rdacarrier
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|a Date Completed 11.09.2007
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|a Date Revised 19.09.2006
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a A polymer dispersion consisting of soft latex spheres with a diameter of 135 nm was used to produce a crystalline film with face-centered cubic (fcc) packing of the spheres. Different from conventional small-molecule and hard-sphere colloidal crystals, the crystalline latex film in the present case is soft (i.e., easily deformable). The structural evolution of this soft colloidal latex film under stretching was investigated by in-situ synchrotron ultra-small-angle X-ray scattering. The film exhibits polycrystalline scattering behavior corresponding to fcc structure. Stretching results not only in a large deformation of the crystallographic structure but also in considerable nonaffine deformation at high draw ratios. The unexpected nonaffine deformation was attributed to slippage between rows of particles and crystalline grain boundaries. The crystalline structure remains intact even at high deformation, suggesting that directional anisotropic colloidal crystallites can be easily produced
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|a Journal Article
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|a Rieger, Jens
|e verfasserin
|4 aut
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|a Roth, Stephan V
|e verfasserin
|4 aut
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1 |
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|a Gehrke, Rainer
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Kong, Xiangming
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 22(2006), 20 vom: 26. Sept., Seite 8285-8
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:22
|g year:2006
|g number:20
|g day:26
|g month:09
|g pages:8285-8
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|d 22
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|h 8285-8
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