Self-assembled monolayers of dipolar nonlinear optical nickel(II) molecules on the Si(100) surface with nanoscale uniformity

The synthesis and structure of a dipolar nonlinear optical bis(salicylaldiminato)Ni(II)-derivatized Schiff base complex chemisorbed on H-terminated Si(100) surfaces is reported. The existence of a monolayer of the derivatized complex chemisorbed on the Si(100) surface is unambiguously confirmed by h...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1999. - 22(2006), 19 vom: 12. Sept., Seite 7952-5
1. Verfasser: Di Bella, Santo (VerfasserIn)
Weitere Verfasser: Condorelli, Guglielmo G, Motta, Alessandro, Ustione, Alessandro, Cricenti, Antonio
Format: Aufsatz
Sprache:English
Veröffentlicht: 2006
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Self-assembled monolayers of dipolar nonlinear optical nickel(II) molecules on the Si(100) surface with nanoscale uniformity 
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520 |a The synthesis and structure of a dipolar nonlinear optical bis(salicylaldiminato)Ni(II)-derivatized Schiff base complex chemisorbed on H-terminated Si(100) surfaces is reported. The existence of a monolayer of the derivatized complex chemisorbed on the Si(100) surface is unambiguously confirmed by high-resolution core-level XPS and AFM/SNOM analyses. The comparison between the optical SNOM images highlights the contribution of the monolayer to the local reflectivity of the sample. Angle-resolved XPS data indicate the presence of chlorine head atoms on the monolayer surface. Altogether, XPS and AFM/SNOM data suggest the formation of a nanoscale uniform, homogeneous, complete, ordered monolayer self-assembled on the Si(100) surface 
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700 1 |a Condorelli, Guglielmo G  |e verfasserin  |4 aut 
700 1 |a Motta, Alessandro  |e verfasserin  |4 aut 
700 1 |a Ustione, Alessandro  |e verfasserin  |4 aut 
700 1 |a Cricenti, Antonio  |e verfasserin  |4 aut 
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