pH sensitive adsorption of polypeptide/sodium dodecyl sulfate mixtures

Neutron reflectivity and surface tension have been used to investigate the pH sensitivity of the adsorption of poly-L-lysine hydrobromide and sodium dodecyl sulfate mixtures at the air-solution interface. The surface tension variation with surfactant concentration is complex, and between the critica...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 22(2006), 18 vom: 29. Aug., Seite 7617-21
1. Verfasser: Penfold, J (VerfasserIn)
Weitere Verfasser: Tucker, I, Thomas, R K, Taylor, D J F, Zhang, X L
Format: Aufsatz
Sprache:English
Veröffentlicht: 2006
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Solutions Water 059QF0KO0R Polylysine 25104-18-1 Sodium Dodecyl Sulfate 368GB5141J
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520 |a Neutron reflectivity and surface tension have been used to investigate the pH sensitivity of the adsorption of poly-L-lysine hydrobromide and sodium dodecyl sulfate mixtures at the air-solution interface. The surface tension variation with surfactant concentration is complex, and between the critical aggregation concentration and critical micellar concentration there is a marked increase in the surface tension. The neutron reflectivity results show that this is associated with a depletion of the surface of polypeptide/surfactant complexes. The variations in the adsorption and surface tension with pH are attributed to changes in the polypeptide conformation at the interface and in solution 
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700 1 |a Thomas, R K  |e verfasserin  |4 aut 
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700 1 |a Zhang, X L  |e verfasserin  |4 aut 
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